Check Google.com for PDF Print
There are many print drver softwares don't know of any free...
here is one..
Print to PDF
Printing to PDF is easy from ANY Application!
With LEADTOOLS ePrint you can print your images, documents, spreadsheets, brochures, anything that can be printed, to any of over 150 file formats (PDF, DOC, TIFF, JPEG, BMP and more). This can be done with or without printing to a paper printer. It's as easy as printing a file from any of your Windows applications!