Can you ping the PLC? If so, your firewall is most likely blocking port 2222. Alot of corporate firewalls block "odd" or "strange" ports to help prevent virus/trojan infections.
Which firewall are you running? Nobody can tell you how to fixxx it until we know what you have...
If you can, try turning the firewall off first, then see if WW can communicate with the PLC. You might need to get your plant IT people involved in correctly configuring your firewall.