In today's world, there are two basic types of I.S. barriers, the zerner type which Keith mentioned, and the galvanic isolation type, which are often called I.S. isolators. This may be what the OP was looking for when he/she asked the difference between an isolator and a barrier. I know that Germany requires the galvanic isolation type in Zone 0, other governments may have local requirements as well, so I would check before purchasing.
The galvanic isolators are more costly up front, but I believe they have a lower total cost. The zerner types have to be maintained, the path to ground MUST be tested at least once per year.
I work at a facility that has both Exp and I.S. all of our older equipment is Exp, and anything after the mid 90's is I.S.. I much prefer I.S.
If you use I.S. then rigid conduit with seal-offs are not required, you can run all your instrument wiring in cable tray.
I used several different brands of barriers over the last decade, but P+F is now my preference.
http://www.pepperl-fuchs.com/
What does intrinsically safe mean?
* The voltage and/or current (power) in an intrinsically safe circuit are so low that a potentially explosive atmosphere cannot be ignited as the result of a short circuit, interruption or earth fault.
* The ignition energy of any spark that may arise is smaller than the minimum ignition energy of the potentially explosive atmosphere.
* Neither a spark nor a thermal effect will ignite the potentially explosive atmosphere.