Ethernet is inherrently peer to peer architecture, so that decision is made.
You can use a peer to peer architecture in what amounts to a master slave mode, simply by how you structure the data inquiries and who asks for data. I have done this using ethernet and GE 90-30 PLCs simply by having the master PLC initiate data inquiries to three identical slave units. The master did overall process and equipment coordination, and the slaves handled the individual machine control. A SCADA system was tied into the same network and obtained over all critical process data from the master. Each PLC, master and slave, had a HMI terminal using the serial connection to a second port on each PLC. That way the HMI response was fast, we could display all the data, and the bandwidth on the ethernet wasn't used up.
You can do this with the Quantum PLC as well. That way you can get fast response to each kiln's or crusher's HMI, the individual process control and protection isn't compromised, and each kiln's proces control is in local logic at that PLC. All the data on speed, loading, temperature, etc. can be collected by the PCs and trended and data logged. I suggest you contact your Modicon / Square D distributor and get them involved early on.