Remember the User tab is configurable. You can put whatever you want in that tab. Rockwell decided to put a few things in there for you to get you started. But you can remove those if you wish and add your own if you like.
Anything in the User tab is a duplicate. I can add the TON instruction to the User tab because I use it a lot. However it will still be in the Timer/Counter tab.
OG
View - Toolbars
Click on SLC 500 Instructions, Click on Customize
Right side is what's currently in the USR tab. Left side is what's available. Use arros in the middle to add or subtract. Then click OK.