Couldnt find ANY faq or manual to describe the use of a CP5603 in connection with an S7-mEC.
However, I quckly made a test project, and managed to setup the CP5603 as a DP master module for the "WinLC RTX EC" controller. And I also managed to attach some DP slaves to the DP network on the CP5603.
So yes, the S7-mEC can be DP master by using the CP5603.