The 'First Scan' is ON all the way through the first regular scan of the logic.
But there is also a 'pre-scan' which happens between turn-on and the first scan mentioned above. Most of the instructions, in their 'help' explanations, define what happens during the 'pre-scan'. One item to note is that locations targeted by an OTE instruction will be turned OFF during the pre-scan. But items referenced only by OTL/OTU instructions retain their condition from the power down state.
There is also a 'power up' routine which has nothing in it by default which can be used.