Been a while since I changed anything on a Controlnet, but as I recall "Scheduling" went something like this:
-PLCs should have required I/O configuration
-All devices should have node numbers configured, be powered up, and connected to network
-All controllers that use the network need to be in program mode.
Open up RSNetworx for Controlnet
Browse and go online to the desired network.
Go file-save which will prompt you to "schedule" the network. Say yes.
Put your processors back to run mode.