What I have learned from other threads, is that Citect requires a socalled SAPI-S7 connection (aka. "user application" in Siemens lingo) to be setup with Simatic Net. That will require a CP5611 or similar. With "MPI cable" maybe you mean the PC Adapter, unfortunately that one cannot be used with Simatic Net.
Another option is to use a 3rd party OPC server that do support the PC adapter. I think KepWare and Deltalogic have OPC servers that support the PC adapter.
That said, to use the PC adapter for a permanent connection is a cludge and does not provide the best performance.