For example they have used Thermocouples on a low temperature range instead of PT's it is well known these are not very accurate at low temperatures/QUOTE]
That's not strictly true. If the reference junction temperatues are close to the measurement junction temperatures then yes, the voltages produced are very small, EDIT : ergo difficult to measure with any degree of accuracy.
However, the reference junction does not have to be 0 deg. C, you can make them whatever temperature you want, so long as you take this into account.
And on the subject of thermocouples, what most people do not realise is that the junction itself produces no potential difference, it can't they are electrically bonded and therefore must be at the same potential.
It is the differing potential difference along the connecting wires due to the Seebeck effect that you can measure, that is why there are always two different metals involved in the "wires" to the thermocouple junction.
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