Welcome to the forum!
You don't state your programming experience level, so I will explain as if to a beginner.
I assume the PLC executes the rungs shown, and many others, on every program scan, and it make one program scan tens, or hundreds, perhaps even a thousand, times per second.
The discrete bit [Bottle Selection 20 OZ L.W. B27:0/11] must be either 0 or 1.
The MOV instruction on Rung 0006 assigns 1800 into T4:80.PRE if and only if the B27:0/11 bit is 1*
The MOV instruction on Rung 0007 assigns 2700 into T4:80.PRE if and only if the B27:0/11 bit is 0**
Since 0 and 1 are the only two possibilities for B27:0/11, exactly one of them will be True on every scan, so the value of T4:80.PRE will be assigned a value, i.e. either 1800 or 2700, on every scan.
So with the program as written, and scanned and executed many times per second, any change made to T4:80.PRE external to those MOV instructions on rung 0006 and 007 will be overwritten, to either 1800 or 2700, by one of those MOV instructions on the next scan, and the overwriting will happen so fast (milliseconds) that you will never see the changed value.
* the XIC instruction means "look for a 1 in my bit, and make the output rung True if that 1 was found.")
** the XIO instruction means "look for a 0 in my bit, and make the output rung True if that 0 was found."