Most PLCs these days support Modbus RTU somewhere along the line. I believe all Schneider PLCs support it. Siemens do but you do not want to know about the price. The new AB Micrologix 1100 has Modbus built in. Very easy with Omron PLCs - the latest ones use CX-Protocol and a standard serial port card that can have 2 x RS232 or 1 x RS232 and 1 x RS422/485 port. I have just set a PLC up with Modbus RTU master RS232 to a Lonworks/Modbus RTU slave converter and the other as an RS422 slave to a BMS system. The new Omron CP1 shoebox that is just about due has Modbus built in.
One can go on about many other brands that support, particularly, Modbus RTU. As far as I am aware it is still the most popular industrial network to a variety of devices in use today.
It is also very easy and convenient to use an RS232 port with an RS232/422/485 converter. I have been using the Adam 4520 for this purpose for years. It is 24VDC powered and is also isolated.