You'll have to change the MPI address on one of the CPUs before you can connect them togher.
Leave one processor with address MPI=2.
Connect to the other processor, go to the hardware configuration for this processor and configure its MPI node address as something different than 2.
To do this, double-click the processors row. A window should open with a bunch of tabs at the top. Select the General tab. There will be a little window that says "Interface". It should list the type (MPI) as well as the address (2). Click the Properties button. On the window that opens select the new address, then close the windows.
Download the hardware configuration to the processor. It will display a window that shows it can connect to a processor with MPI address of 2 (the current address of the one you are connected to). Connect to this processor and download. After you have downloaded to it, it will now have the new MPI address.
Now connect the two processor's together.