Here is one site dedicated to S5 programming; it will give you some examples of STL and LAD programming on S5 PLCs: http://www.plcman.co.uk/
But for a complete description of Step 5 instructions in all views (STL, CSF and LAD), I recommend you download a pdf manual on S5 processors from the Siemens support website, such as :
SIMATIC S5 S5-115U Programmable Controller (6ES5 998-0UF23.pdf)Here is an example of what you can find in the Step 5 operations chapter: