In 45 hours you will only be able to cover a few of the topics in detail, or you could do a summary of many of them. I would suggest that you pick what you want to cover based on what would be most useful to the students.
NEC Article 100 (Definitions essential to the proper application of the Code) is a good place to start. From there, pick out the topics that apply to the customers - if they are potential electricians, then you might cover these articles:
110-26 Working Clearances
210 Branch Circuits
220 Branch Circuit Calculations
230 Services
250 Grounding
300 Wiring Methods (include 310-16 Conductor Ampacity)
If they are maintenance guys, then cover:
240 Overcurrent Protection (include fuse types, circuit breakers)
250 Grounding
310-16 Conductor Ampacity
430 Motors
440 Air Conditioning & refrigeration Equipment
450 Transformers