Some options spring to mind:
1) Connect the reader to a serial interface on your PLC and read in the data that way.
2) Write an program to run on your SCADA PC to read the bar code into a text box that has a DDE link. In RSVeiw32 set up a DDE link to your application.
3) Get an OPC server APP for your reader.
In theory, you could write some VBA code in RSView32 with the MScomm control but if you are polling the reader all the time then nothing else will work as RSview32 is single threaded.
Nick