Natanam, look in the 5/80 installation manual or online for the steps to take. You already have a backup so that is the most important as long as you configure the appropriate switches for your application.
Inside the program code backup should also have information as to the setup configuration of the old 5/80
Bhavdeep, simple "heartbeat" logic between the primary, secondary and HMI which will provide a means to monitor the plc's and auto-switch to secondary if primary fails. I believe there were several tech notes about this on the rockwell website a few years ago. (That's how long it has been since I set up that type of redundant system) If you can't find anything there or from others on this site, PM me and I will dig out some of my old code on my next trip home in a couple of weeks. I won't do the work for you but I will be happy to assist and make suggestions.