I have just started playing with the Moxa MGate EIP3270, which converts RS-232 DF1 communication to Ethernet PCCC comms. This is a dual port unit, that would connect 2 DF1 converters. They make a single channel unit as well. One of those at each 5/04 would put them on ethernet. At that point, you could use RSLinx to establish an OPC connection to the PLC, and whatever software on the PC (RS Historian? Haven't worked with it, so not sure) or even write a small VB app to pull the data from Linx and stuff it into your database.