DeviceNet was a good solution for the problems of its time, but that time has passed. The main issue was that in industrial networking, you were highly likely to run into a situation where the network cabling was going to be in the same space/raceway as power wiring, so the insulation would need to be rated for 600V even though the network voltage was only 24VDC. DeviceNet cabling solved that problem. It also solved some noise immunity problems by "brute force" signals based on current rather than shielding, which created issues of voltage drop, leading to a somewhat complicated system of trunk cables, branch cables and maximum distance limitations to power supplies. Once you understood all of that and got the right design tools it wasn't hard to implement, but the learning curve was steep for beginners, often resulting in costly mistakes. Still, it was the best solution for a host of other industrial networking issues for a long time. In Europe, the same issues had lead to Siemens developing Profibus, but that never got a good foothold in North America. There are some installations sure, but nowhere near what Dnet has.
What has changed all of that now is the development and release of good quality Ethernet cable that has 600V rated insulation. Ethernet /IP is the Ethernet protocol standard released and supported by the same people in charge of Devicenet standards, the ODVA (Open Devicenet Vendors Assoc.). If you are going to start learning more about industrial networking, I would recommend going that route. Devicenet is not going anywhere for a long time because, as mentioned, the installed base in NA is huge. But the future is Ethernet, and most likely Ethernet /IP.
That said, because the installed base is so big, and because most people will be migrating to Ethernet, there is some intrinsic value in learning all of the complexities of Dnet, because as my generation ages out if the workforce, you young whippersnappers will need at least a few people who understand it 20 years from now...
Hey! you kids get off of my lawn!