If on the last screenshot, you only had the CP5511 and the ET200M connected, then it does not look good. You should have been able to see the slave.
Some ideas:
Check if the node number is correctly set.
Check the HW configuration in STEP7, save and compile, and download anew to the CPU.
Try to attach all, CP5511, S7 CPU and ET200M and see if the slave appears in the diagnostics together with the CPU and the PCs node addresses.
Check you cable and other hardware with another, working, Profibus installation.
Try to set the baudrate to 187.5k.
Some ideas:
Check if the node number is correctly set.
Check the HW configuration in STEP7, save and compile, and download anew to the CPU.
Try to attach all, CP5511, S7 CPU and ET200M and see if the slave appears in the diagnostics together with the CPU and the PCs node addresses.
Check you cable and other hardware with another, working, Profibus installation.
Try to set the baudrate to 187.5k.