Open SyCon.net. During installation you should have set up an Administrator password for the software; I use the same password as my Windows login for simplicity.
A default and empty project named "Untitled.spj" should be open, with a netProject pane, a netDevice pane, and a device library pane on the right side of the screen.
In the device library's Fieldbus tab, expand the PROFINET IO folder, then the Gateway / Stand-Alone Slave folder.
Scroll down and select the NT100-XX-XX device, and drag it into the netDevice pane until a [+] appears over the network bus line and you can "drop" the device into that window.
Right-click on the device and select Configuration -> Gateway
A new configuration windo will open, with a navigation tree on the left. Select Configuration, and a Settings screen will appear.
On the left side, select the Primary network (Port X2) from the dropdown to be "PROFINET IO Controller"
On the right side, select the Secondary network (Port X3) from the dropdown to be "DeviceNet Slave".
That should narrow down the available firmware selection to only a file named "NTPNMDNS.NXF".
Set the Mapping Cycle time to a more realistic value than 1 ms; I recommend 20.
Click the Apply button in the lower right of the Settings screen, then the OK button to close that window.
Now that you have configured the appropriate network choices, when you right-click on the netTAP object in the network layout window, the Configuration folder will have both ProfiNet IO Controller and DeviceNet Slave available for configuration.
Select Configuration -> DeviceNet Slave to configure the essentials of the DeviceNet network.
Under the Bus section, select a MAC ID and a baud rate. I typically make my DeviceNet scanner Node 0, so it make sense to start your NetTAP devices as Node 1 or higher. I would choose 125 kb/s to start with because that is the most forgiving of cabling or termination errors.
Use the scroll bar to scroll down to reveal the I/O size settings. The Consumed and Produced data sizes are default 8 bytes, but can be set for any value between 1 and 255 bytes.
Select the other Configuration catgory in the navigation area to examine the Signal Configuration. For experimentation, I set the I/O sizes to 64 bytes each.
Downloading just this basic configuration *should* allow you to browse the NT100 in RSLinx and RSNetworx for DeviceNet, and to map a polled I/O connection to the PLC-5 data table.