*sigh*
You are not sure how to accomplish the task, but you have already gone and spent quite a bit of money on hardware !?
And you have two CP342-5's
and DP couplers ! And you wrote "coupler
s", so you have two of these too ?
Honestly, the onboard DP ports would have been enough, eventuelly with the use of one DP coupler between the two CPUs.
You could theoretically use one CP342-5 in the existing master CPU, to avoid having to change the existing master system on that CPU. But you would still have to change the HW Configuration. Notice that the performance will be somewhat lower than when using the onboard DP port.
PUT/GET will be even slower.
Future advice:
Clearly define the task to accomplish.
Investigate the possible ways to accomplish the task.
Pick one of the ways, and perfom the steps needed to finish the task (including purchasing stuff).
In that order.